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class="container" data-v-4885b148><div class="aside" data-v-4885b148><div class="aside-curtain" data-v-4885b148></div><div class="aside-container" data-v-4885b148><div class="aside-content" data-v-4885b148><div class="VPDocAside" data-v-4885b148 data-v-7045d2d5><!--[--><!--]--><!--[--><!--]--><div class="VPDocAsideOutline" role="navigation" data-v-7045d2d5 data-v-35301578><div class="content" data-v-35301578><div class="outline-marker" data-v-35301578></div><div class="outline-title" role="heading" aria-level="2" data-v-35301578>TOC</div><nav aria-labelledby="doc-outline-aria-label" data-v-35301578><span class="visually-hidden" id="doc-outline-aria-label" data-v-35301578> Table of Contents for current page </span><ul class="root" data-v-35301578 data-v-cc4b0507><!--[--><!--]--></ul></nav></div></div><!--[--><!--]--><div class="spacer" data-v-7045d2d5></div><!--[--><!--]--><!----><!--[--><!--]--><!--[--><!--[--><!--[--><!--[--><div class="VPDocAsideSponsors"><div class="VPSponsors vp-sponsor aside"><!--[--><section class="vp-sponsor-section"><!----><div class="VPSponsorsGrid vp-sponsor-grid medium"><!--[--><div class="vp-sponsor-grid-item"><a class="vp-sponsor-grid-link" target="_blank" rel="sponsored noopener"><article class="vp-sponsor-grid-box"><h4 class="visually-hidden"></h4><img class="vp-sponsor-grid-image" src="https://jsd.toshiki.dev/gh/andatoshiki/toshiki-notebook@master/assets/logo/sponsor/telegram.png"></article></a></div><!--]--></div></section><!--]--></div></div><!--]--><!--]--><!--]--><!--]--></div></div></div></div><div class="content" data-v-4885b148><div class="content-container" data-v-4885b148><!--[--><!--]--><!----><main class="main" data-v-4885b148><div style="position:relative;" class="vp-doc _academic_chemistry_problems_03-02-3" data-v-4885b148><div><h1 id="problem-03-02-3" tabindex="-1">Problem 03-02-3 <a class="header-anchor" href="#problem-03-02-3" aria-label="Permalink to "Problem 03-02-3""></a></h1><div><section class="border-b-1 border-[var(--vp-c-divider)] w-full border-b-solid mt-[24px] pb-[12px] flex gap-[12px] mb-[12px] flex-wrap max-w-[85%]"><div class="flex gap-[4px] items-center"><svg style="display:inline-block;" viewBox="0 0 16 16" width="1.2em" height="1.2em"><path fill="currentColor" d="M8 16A8 8 0 1 1 8 0a8 8 0 0 1 0 16m.847-8.145a2.502 2.502 0 1 0-1.694 0C5.471 8.261 4 9.775 4 11c0 .395.145.995 1 .995h6c.855 0 1-.6 1-.995c0-1.224-1.47-2.74-3.153-3.145"></path></svg> Author:<span>Anda Toshiki</span></div><!----><div class="flex gap-[4px] items-center"><svg style="display:inline-block;" viewBox="0 0 15 15" width="1.2em" height="1.2em"><path fill="currentColor" fill-rule="evenodd" d="M1.903 7.297c0 3.044 2.207 5.118 4.686 5.547a.521.521 0 1 1-.178 1.027C3.5 13.367.861 10.913.861 7.297c0-1.537.699-2.745 1.515-3.663c.585-.658 1.254-1.193 1.792-1.602H2.532a.5.5 0 0 1 0-1h3a.5.5 0 0 1 .5.5v3a.5.5 0 0 1-1 0V2.686l-.001.002c-.572.43-1.27.957-1.875 1.638c-.715.804-1.253 1.776-1.253 2.97m11.108.406c0-3.012-2.16-5.073-4.607-5.533a.521.521 0 1 1 .192-1.024c2.874.54 5.457 2.98 5.457 6.557c0 1.537-.699 2.744-1.515 3.663c-.585.658-1.254 1.193-1.792 1.602h1.636a.5.5 0 1 1 0 1h-3a.5.5 0 0 1-.5-.5v-3a.5.5 0 1 1 1 0v1.845h.002c.571-.432 1.27-.958 1.874-1.64c.715-.803 1.253-1.775 1.253-2.97" clip-rule="evenodd"></path></svg> Updated:<span>2 minutes ago</span></div><div class="flex gap-[4px] items-center"><svg style="display:inline-block;" viewBox="0 0 16 16" width="1.2em" height="1.2em"><path fill="currentColor" d="M9.293 0H4a2 2 0 0 0-2 2v12a2 2 0 0 0 2 2h8a2 2 0 0 0 2-2V4.707A1 1 0 0 0 13.707 4L10 .293A1 1 0 0 0 9.293 0M9.5 3.5v-2l3 3h-2a1 1 0 0 1-1-1M5.485 6.879l1.036 4.144l.997-3.655a.5.5 0 0 1 .964 0l.997 3.655l1.036-4.144a.5.5 0 0 1 .97.242l-1.5 6a.5.5 0 0 1-.967.01L8 9.402l-1.018 3.73a.5.5 0 0 1-.967-.01l-1.5-6a.5.5 0 1 1 .97-.242z"></path></svg> Words:<span>246</span></div><div class="flex gap-[4px] items-center"><svg style="display:inline-block;" viewBox="0 0 20 20" width="1.2em" height="1.2em"><path fill="currentColor" d="M10 0a10 10 0 1 0 10 10A10 10 0 0 0 10 0m2.5 14.5L9 11V4h2v6l3 3z"></path></svg> Reading:<span>1 min</span></div></section></div><h2 id="question" tabindex="-1">Question <a class="header-anchor" href="#question" aria-label="Permalink to "Question""></a></h2><p class="katex-block"><span class="katex-display"><span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML" display="block"><semantics><mrow><mn>2</mn><mi mathvariant="normal">X</mi><mo stretchy="false">(</mo><mi>g</mi><mo stretchy="false">)</mo><mo>+</mo><mn>2</mn><mi mathvariant="normal">Y</mi><mo stretchy="false">(</mo><mi>g</mi><mo stretchy="false">)</mo><mo>→</mo><mi mathvariant="normal">Q</mi><mo stretchy="false">(</mo><mi>g</mi><mo stretchy="false">)</mo><mo>+</mo><mn>2</mn><mi mathvariant="normal">R</mi><mo stretchy="false">(</mo><mi>g</mi><mo stretchy="false">)</mo></mrow><annotation encoding="application/x-tex">2 \mathrm{X}(g)+2 \mathrm{Y}(g) \rightarrow \mathrm{Q}(g)+2 \mathrm{R}(g) </annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mord">2</span><span class="mord mathrm">X</span><span class="mopen">(</span><span class="mord mathnormal" style="margin-right:0.03588em;">g</span><span class="mclose">)</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mbin">+</span><span class="mspace" style="margin-right:0.2222em;"></span></span><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mord">2</span><span class="mord mathrm" style="margin-right:0.025em;">Y</span><span class="mopen">(</span><span class="mord mathnormal" style="margin-right:0.03588em;">g</span><span class="mclose">)</span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mrel">→</span><span class="mspace" style="margin-right:0.2778em;"></span></span><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mord mathrm">Q</span><span class="mopen">(</span><span class="mord mathnormal" style="margin-right:0.03588em;">g</span><span class="mclose">)</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mbin">+</span><span class="mspace" style="margin-right:0.2222em;"></span></span><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mord">2</span><span class="mord mathrm">R</span><span class="mopen">(</span><span class="mord mathnormal" style="margin-right:0.03588em;">g</span><span class="mclose">)</span></span></span></span></span></p><p>The reaction represented above is found to be second order with respect to <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mi mathvariant="normal">X</mi></mrow><annotation encoding="application/x-tex">\mathrm{X}</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:0.6833em;"></span><span class="mord mathrm">X</span></span></span></span> and first order with respect to <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mi mathvariant="normal">Y</mi></mrow><annotation encoding="application/x-tex">\mathrm{Y}</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:0.6833em;"></span><span class="mord mathrm" style="margin-right:0.025em;">Y</span></span></span></span>.</p><p>What happens to the rate of the reaction when <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mo stretchy="false">[</mo><mi mathvariant="normal">X</mi><mo stretchy="false">]</mo></mrow><annotation encoding="application/x-tex">[\mathrm{X}]</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mopen">[</span><span class="mord mathrm">X</span><span class="mclose">]</span></span></span></span> is halved and <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mo stretchy="false">[</mo><mi mathvariant="normal">Y</mi><mo stretchy="false">]</mo></mrow><annotation encoding="application/x-tex">[\mathrm{Y}]</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mopen">[</span><span class="mord mathrm" style="margin-right:0.025em;">Y</span><span class="mclose">]</span></span></span></span> is doubled?</p><ul class="contains-task-list"><li class="task-list-item"><input class="task-list-item-checkbox" disabled="" type="checkbox"> It increases by a factor of 4.</li><li class="task-list-item"><input class="task-list-item-checkbox" checked="" disabled="" type="checkbox"> It decreases by a factor of 2.</li><li class="task-list-item"><input class="task-list-item-checkbox" disabled="" type="checkbox"> It decreases by a factor of 4.</li><li class="task-list-item"><input class="task-list-item-checkbox" disabled="" type="checkbox"> It does not change.</li></ul><h2 id="solution" tabindex="-1">Solution <a class="header-anchor" href="#solution" aria-label="Permalink to "Solution""></a></h2><p>To solve this problem, let's first write out the rate law for the reaction. According to the text, the reaction is second order with respect to <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mi mathvariant="normal">X</mi></mrow><annotation encoding="application/x-tex">\mathrm{X}</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:0.6833em;"></span><span class="mord mathrm">X</span></span></span></span> and first order with respect to <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mi mathvariant="normal">Y</mi></mrow><annotation encoding="application/x-tex">\mathrm{Y}</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:0.6833em;"></span><span class="mord mathrm" style="margin-right:0.025em;">Y</span></span></span></span>, so the rate law is rate <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mo>=</mo><mi>k</mi><mo stretchy="false">[</mo><mi mathvariant="normal">X</mi><msup><mo stretchy="false">]</mo><mn>2</mn></msup><mo stretchy="false">[</mo><mi mathvariant="normal">Y</mi><mo stretchy="false">]</mo></mrow><annotation encoding="application/x-tex">=k[\mathrm{X}]^2[\mathrm{Y}]</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:0.3669em;"></span><span class="mrel">=</span><span class="mspace" style="margin-right:0.2778em;"></span></span><span class="base"><span class="strut" style="height:1.0641em;vertical-align:-0.25em;"></span><span class="mord mathnormal" style="margin-right:0.03148em;">k</span><span class="mopen">[</span><span class="mord mathrm">X</span><span class="mclose"><span class="mclose">]</span><span class="msupsub"><span class="vlist-t"><span class="vlist-r"><span class="vlist" style="height:0.8141em;"><span style="top:-3.063em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span></span></span></span></span><span class="mopen">[</span><span class="mord mathrm" style="margin-right:0.025em;">Y</span><span class="mclose">]</span></span></span></span></p><p>Now, let's think about how the rate changes when <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mo stretchy="false">[</mo><mi mathvariant="normal">X</mi><mo stretchy="false">]</mo></mrow><annotation encoding="application/x-tex">[\mathrm{X}]</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mopen">[</span><span class="mord mathrm">X</span><span class="mclose">]</span></span></span></span> is halved and <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mo stretchy="false">[</mo><mi mathvariant="normal">Y</mi><mo stretchy="false">]</mo></mrow><annotation encoding="application/x-tex">[\mathrm{Y}]</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mopen">[</span><span class="mord mathrm" style="margin-right:0.025em;">Y</span><span class="mclose">]</span></span></span></span> is doubled. Since <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mo stretchy="false">[</mo><mi mathvariant="normal">X</mi><mo stretchy="false">]</mo></mrow><annotation encoding="application/x-tex">[\mathrm{X}]</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mopen">[</span><span class="mord mathrm">X</span><span class="mclose">]</span></span></span></span> is raised to the second power in the rate law, halving <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mo stretchy="false">[</mo><mi mathvariant="normal">X</mi><mo stretchy="false">]</mo></mrow><annotation encoding="application/x-tex">[\mathrm{X}]</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mopen">[</span><span class="mord mathrm">X</span><span class="mclose">]</span></span></span></span> decreases the reaction rate by a factor of 4 . Similarly, since <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mo stretchy="false">[</mo><mi mathvariant="normal">Y</mi><mo stretchy="false">]</mo></mrow><annotation encoding="application/x-tex">[\mathrm{Y}]</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mopen">[</span><span class="mord mathrm" style="margin-right:0.025em;">Y</span><span class="mclose">]</span></span></span></span> is raised to the first power, doubling <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mo stretchy="false">[</mo><mi mathvariant="normal">Y</mi><mo stretchy="false">]</mo></mrow><annotation encoding="application/x-tex">[\mathrm{Y}]</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mopen">[</span><span class="mord mathrm" style="margin-right:0.025em;">Y</span><span class="mclose">]</span></span></span></span> increases the reaction rate by a factor of 2 . Combined, these changes result in the reaction rate decreasing by a factor of 2 overall. So, when <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mo stretchy="false">[</mo><mi mathvariant="normal">X</mi><mo stretchy="false">]</mo></mrow><annotation encoding="application/x-tex">[\mathrm{X}]</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mopen">[</span><span class="mord mathrm">X</span><span class="mclose">]</span></span></span></span> is halved and <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mo stretchy="false">[</mo><mi mathvariant="normal">Y</mi><mo stretchy="false">]</mo></mrow><annotation encoding="application/x-tex">[\mathrm{Y}]</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mopen">[</span><span class="mord mathrm" style="margin-right:0.025em;">Y</span><span class="mclose">]</span></span></span></span> is doubled, the rate of the reaction decreases by a factor of 2 .</p></div></div></main><footer class="VPDocFooter" data-v-4885b148 data-v-10ef07da><!--[--><!--[--><!--[--><!--[--><!----><!--]--><!--]--><!--]--><!--]--><div class="edit-info" data-v-10ef07da><div class="edit-link" data-v-10ef07da><a class="VPLink link vp-external-link-icon no-icon edit-link-button" href="https://github.com/andatoshiki/toshiki-notebook/edit/master/docs/academic/chemistry/problems/03-02-3.md" target="_blank" rel="noreferrer" data-v-10ef07da><!--[--><svg xmlns="http://www.w3.org/2000/svg" viewbox="0 0 24 24" class="edit-link-icon" aria-label="edit icon" data-v-10ef07da><path d="M18,23H4c-1.7,0-3-1.3-3-3V6c0-1.7,1.3-3,3-3h7c0.6,0,1,0.4,1,1s-0.4,1-1,1H4C3.4,5,3,5.4,3,6v14c0,0.6,0.4,1,1,1h14c0.6,0,1-0.4,1-1v-7c0-0.6,0.4-1,1-1s1,0.4,1,1v7C21,21.7,19.7,23,18,23z"></path><path d="M8,17c-0.3,0-0.5-0.1-0.7-0.3C7,16.5,6.9,16.1,7,15.8l1-4c0-0.2,0.1-0.3,0.3-0.5l9.5-9.5c1.2-1.2,3.2-1.2,4.4,0c1.2,1.2,1.2,3.2,0,4.4l-9.5,9.5c-0.1,0.1-0.3,0.2-0.5,0.3l-4,1C8.2,17,8.1,17,8,17zM9.9,12.5l-0.5,2.1l2.1-0.5l9.3-9.3c0.4-0.4,0.4-1.1,0-1.6c-0.4-0.4-1.2-0.4-1.6,0l0,0L9.9,12.5z M18.5,2.5L18.5,2.5L18.5,2.5z"></path></svg> Edit this page on GitHub<!--]--></a></div><div class="last-updated" data-v-10ef07da><p class="VPLastUpdated" data-v-10ef07da data-v-d785740a>Last updated: <time datetime="2024-09-15T16:31:50.000Z" data-v-d785740a></time></p></div></div><nav class="prev-next" data-v-10ef07da><div class="pager" data-v-10ef07da><a class="pager-link prev" href="/academic/chemistry/problems/03-02-2" data-v-10ef07da><span class="desc" data-v-10ef07da>Previous page</span><span class="title" data-v-10ef07da>Problem: 03-02-2</span></a></div><div class="pager" data-v-10ef07da><!----></div></nav></footer><!--[--><!--[--><!--[--><div id="comment-container"></div><!--]--><!--]--><!--]--></div></div></div><!--[--><!--]--></div></div><footer class="VPFooter has-sidebar" data-v-89207109 data-v-d607cddc><div class="container" data-v-d607cddc><p class="message" data-v-d607cddc>Copyright © 2023-2024 <a href="https://github.com/andatoshiki">Anda Toshiki</a>, <a href="https://github.com/lolilab">LoliLab</a> and <a href="https://github.com/toshikidev">Toshiki Dev</a> present <br /><span id="siteruntime_span"></span></p><p class="copyright" data-v-d607cddc>Wrote with <span class="heart">💓</span> with 🌵 by <a href="https://toshiki.dev">Anda Toshiki</a> at <code>root@andatoshiki:/~</code> in the innovative HQ of <a href="https://asu.edu">ASU</a></p></div></footer><!--[--><!--]--></div></div>
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