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href="#presentation-problem-02-20" aria-hidden="true">#</a></h1><h2 id="question" tabindex="-1">Question <a class="header-anchor" href="#question" aria-hidden="true">#</a></h2><p>At <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mn>500</mn><mrow><mtext> </mtext><mi mathvariant="normal">K</mi></mrow></mrow><annotation encoding="application/x-tex">500 \mathrm{~K}</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:0.6833em;"></span><span class="mord">500</span><span class="mord"><span class="mspace nobreak"> </span><span class="mord mathrm">K</span></span></span></span></span> in the presence of a copper surface, ethanol decomposes according to the equation</p><p class="katex-block"><span class="katex-display"><span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML" display="block"><semantics><mrow><msub><mi mathvariant="normal">C</mi><mn>2</mn></msub><msub><mi mathvariant="normal">H</mi><mn>5</mn></msub><mrow><mi mathvariant="normal">O</mi><mi mathvariant="normal">H</mi></mrow><mo stretchy="false">(</mo><mi mathvariant="normal">g</mi><mo stretchy="false">)</mo><mo>⟶</mo><msub><mrow><mi mathvariant="normal">C</mi><mi mathvariant="normal">H</mi></mrow><mn>3</mn></msub><mrow><mi mathvariant="normal">C</mi><mi mathvariant="normal">H</mi><mi mathvariant="normal">O</mi></mrow><mo stretchy="false">(</mo><mi>g</mi><mo stretchy="false">)</mo><mo>+</mo><msub><mi mathvariant="normal">H</mi><mn>2</mn></msub><mo stretchy="false">(</mo><mi>g</mi><mo stretchy="false">)</mo></mrow><annotation encoding="application/x-tex">\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}(\mathrm{g}) \longrightarrow \mathrm{CH}_3 \mathrm{CHO}(g)+\mathrm{H}_2(g) </annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mord"><span class="mord mathrm">C</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">H</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">5</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">OH</span></span><span class="mopen">(</span><span class="mord mathrm" style="margin-right:0.01389em;">g</span><span class="mclose">)</span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mrel">⟶</span><span class="mspace" style="margin-right:0.2778em;"></span></span><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mord"><span class="mord"><span class="mord mathrm">CH</span></span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">3</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">CHO</span></span><span class="mopen">(</span><span class="mord mathnormal" style="margin-right:0.03588em;">g</span><span class="mclose">)</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mbin">+</span><span class="mspace" style="margin-right:0.2222em;"></span></span><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mord"><span class="mord mathrm">H</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mopen">(</span><span class="mord mathnormal" style="margin-right:0.03588em;">g</span><span class="mclose">)</span></span></span></span></span></p><p>The pressure of <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><msub><mi mathvariant="normal">C</mi><mn>2</mn></msub><msub><mi mathvariant="normal">H</mi><mn>5</mn></msub><mrow><mi mathvariant="normal">O</mi><mi mathvariant="normal">H</mi></mrow></mrow><annotation encoding="application/x-tex">\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:0.8333em;vertical-align:-0.15em;"></span><span class="mord"><span class="mord mathrm">C</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">H</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">5</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">OH</span></span></span></span></span> was measured as a function of time and the following data were obtained:</p><table><thead><tr><th>Time (s)</th><th><span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><msub><mi>P</mi><mrow><msub><mi mathvariant="normal">C</mi><mn>2</mn></msub><msub><mi mathvariant="normal">H</mi><mn>5</mn></msub><mrow><mi mathvariant="normal">O</mi><mi mathvariant="normal">H</mi></mrow></mrow></msub><mtext> (torr) </mtext></mrow><annotation encoding="application/x-tex">P_{\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}} \text { (torr) }</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1.0001em;vertical-align:-0.2501em;"></span><span class="mord"><span class="mord mathnormal" style="margin-right:0.13889em;">P</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3283em;"><span style="top:-2.55em;margin-left:-0.1389em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight"><span class="mord mtight"><span class="mord mathrm mtight">C</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3173em;"><span style="top:-2.357em;margin-left:0em;margin-right:0.0714em;"><span class="pstrut" style="height:2.5em;"></span><span class="sizing reset-size3 size1 mtight"><span class="mord mtight">2</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.143em;"><span></span></span></span></span></span></span><span class="mord mtight"><span class="mord mathrm mtight">H</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3173em;"><span style="top:-2.357em;margin-left:0em;margin-right:0.0714em;"><span class="pstrut" style="height:2.5em;"></span><span class="sizing reset-size3 size1 mtight"><span class="mord mtight">5</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.143em;"><span></span></span></span></span></span></span><span class="mord mtight"><span class="mord mathrm mtight">OH</span></span></span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.2501em;"><span></span></span></span></span></span></span><span class="mord text"><span class="mord"> (torr) </span></span></span></span></span></th></tr></thead><tbody><tr><td>0</td><td>250.</td></tr><tr><td>100.</td><td>237</td></tr><tr><td>200.</td><td>224</td></tr><tr><td>300.</td><td>211</td></tr><tr><td>400.</td><td>198</td></tr><tr><td>500.</td><td>185</td></tr></tbody></table><p><strong>Since the pressure of a gas is directly proportional to the concentration of gas</strong>, we can express the rate law for a gaseous reaction in terms of partial pressures. Using the above data, deduce the rate law, the integrated rate law, and the value of the rate constant, all in terms of pressure units in atm and time in seconds. Predict the pressure of <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><msub><mi mathvariant="normal">C</mi><mn>2</mn></msub><msub><mi mathvariant="normal">H</mi><mn>5</mn></msub><mrow><mi mathvariant="normal">O</mi><mi mathvariant="normal">H</mi></mrow></mrow><annotation encoding="application/x-tex">\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:0.8333em;vertical-align:-0.15em;"></span><span class="mord"><span class="mord mathrm">C</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">H</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">5</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">OH</span></span></span></span></span> after <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mn>900.</mn><mi mathvariant="normal">s</mi></mrow><annotation encoding="application/x-tex">900 . \mathrm{s}</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:0.6444em;"></span><span class="mord">900.</span><span class="mord mathrm">s</span></span></span></span> from the start of the reaction. (Hint: To determine the order of the reaction with respect to <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><msub><mi mathvariant="normal">C</mi><mn>2</mn></msub><msub><mi mathvariant="normal">H</mi><mn>5</mn></msub><mrow><mi mathvariant="normal">O</mi><mi mathvariant="normal">H</mi></mrow></mrow><annotation encoding="application/x-tex">\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:0.8333em;vertical-align:-0.15em;"></span><span class="mord"><span class="mord mathrm">C</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">H</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">5</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">OH</span></span></span></span></span>, compare how the pressure of <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><msub><mi mathvariant="normal">C</mi><mn>2</mn></msub><msub><mi mathvariant="normal">H</mi><mn>5</mn></msub><mrow><mi mathvariant="normal">O</mi><mi mathvariant="normal">H</mi></mrow></mrow><annotation encoding="application/x-tex">\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:0.8333em;vertical-align:-0.15em;"></span><span class="mord"><span class="mord mathrm">C</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">H</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">5</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">OH</span></span></span></span></span> decreases with each time listing.)</p><h2 id="solution" tabindex="-1">Solution <a class="header-anchor" href="#solution" aria-hidden="true">#</a></h2><p><img src="https://r2.toshiki.dev/image/chemistry/solution1.png" alt="solution graph" data-zoomable=""></p><p>Due to the fact that the graph of <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mi mathvariant="normal">p</mi><mrow><mo fence="true">[</mo><msub><mi mathvariant="normal">O</mi><mn>2</mn></msub><mo fence="true">]</mo></mrow></mrow><annotation encoding="application/x-tex">\mathrm{p}\left[\mathrm{O}_2\right]</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mord mathrm">p</span><span class="mspace" style="margin-right:0.1667em;"></span><span class="minner"><span class="mopen delimcenter" style="top:0em;">[</span><span class="mord"><span class="mord mathrm">O</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mclose delimcenter" style="top:0em;">]</span></span></span></span></span> over time is showing <span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><msup><mi mathvariant="normal">R</mi><mn>2</mn></msup></mrow><annotation encoding="application/x-tex">\mathrm{R}^2</annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:0.8141em;"></span><span class="mord"><span class="mord mathrm">R</span><span class="msupsub"><span class="vlist-t"><span class="vlist-r"><span class="vlist" style="height:0.8141em;"><span style="top:-3.063em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span></span></span></span></span></span></span></span> value of 1 we know we have a zero-order reaction. Therefore:</p><p class="katex-block"><span class="katex-display"><span class="katex"><span class="katex-mathml"><math xmlns="http://www.w3.org/1998/Math/MathML" display="block"><semantics><mtable rowspacing="0.25em" columnalign="right left" columnspacing="0em"><mtr><mtd><mstyle scriptlevel="0" displaystyle="true"><mrow></mrow></mstyle></mtd><mtd><mstyle scriptlevel="0" displaystyle="true"><mrow><mrow></mrow><mi mathvariant="normal">k</mi><mo>=</mo><mfrac><mrow><msub><mi mathvariant="normal">p</mi><mn>0</mn></msub><mrow><mo fence="true">[</mo><msub><mi mathvariant="normal">C</mi><mn>2</mn></msub><msub><mi mathvariant="normal">H</mi><mn>5</mn></msub><mrow><mi mathvariant="normal">O</mi><mi mathvariant="normal">H</mi></mrow><mo fence="true">]</mo></mrow><mo>−</mo><mi mathvariant="normal">p</mi><mrow><mo fence="true">[</mo><msub><mi mathvariant="normal">C</mi><mn>2</mn></msub><msub><mi mathvariant="normal">H</mi><mn>5</mn></msub><mrow><mi mathvariant="normal">O</mi><mi mathvariant="normal">H</mi></mrow><mo fence="true">]</mo></mrow></mrow><mi mathvariant="normal">t</mi></mfrac><mo>=</mo><mfrac><mrow><mn>250</mn><mtext> torr </mtext><mo>−</mo><mn>185</mn><mtext> torr </mtext></mrow><mrow><mn>500</mn><mrow><mtext> </mtext><mi mathvariant="normal">s</mi></mrow></mrow></mfrac><mo>=</mo><mn>0.13</mn><msup><mtext> torr s </mtext><mrow><mo>−</mo><mn>1</mn></mrow></msup></mrow></mstyle></mtd></mtr><mtr><mtd><mstyle scriptlevel="0" displaystyle="true"><mrow></mrow></mstyle></mtd><mtd><mstyle scriptlevel="0" displaystyle="true"><mrow><mrow></mrow><mi mathvariant="normal">k</mi><mo>=</mo><mn>0.13</mn><mtext> torr s </mtext><msup><mi mathvariant="normal">s</mi><mrow><mo>−</mo><mn>1</mn></mrow></msup><mo>×</mo><mfrac><mrow><mn>1</mn><mrow><mtext> </mtext><mi mathvariant="normal">a</mi><mi mathvariant="normal">t</mi><mi mathvariant="normal">m</mi></mrow></mrow><mrow><mn>760</mn><mtext> torr </mtext></mrow></mfrac><mo>=</mo><mn>1.71</mn><mo>×</mo><mn>1</mn><msup><mn>0</mn><mrow><mo>−</mo><mn>4</mn></mrow></msup><mrow><mtext> </mtext><mi mathvariant="normal">a</mi><mi mathvariant="normal">t</mi><mi mathvariant="normal">m</mi></mrow><msup><mrow><mtext> </mtext><mi mathvariant="normal">s</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup></mrow></mstyle></mtd></mtr><mtr><mtd><mstyle scriptlevel="0" displaystyle="true"><mrow></mrow></mstyle></mtd><mtd><mstyle scriptlevel="0" displaystyle="true"><mrow><mrow></mrow><mtext> rate </mtext><mo>=</mo><mi mathvariant="bold">k</mi></mrow></mstyle></mtd></mtr><mtr><mtd><mstyle scriptlevel="0" displaystyle="true"><mrow></mrow></mstyle></mtd><mtd><mstyle scriptlevel="0" displaystyle="true"><mrow><mrow></mrow><mi mathvariant="normal">p</mi><mrow><mo fence="true">(</mo><msub><mi mathvariant="normal">C</mi><mn>2</mn></msub><msub><mi mathvariant="normal">H</mi><mn>5</mn></msub><mrow><mi mathvariant="normal">O</mi><mi mathvariant="normal">H</mi></mrow><mo fence="true">)</mo></mrow><mo>=</mo><mo>−</mo><mrow><mi mathvariant="normal">k</mi><mi mathvariant="normal">t</mi></mrow><mo>+</mo><msub><mi mathvariant="normal">p</mi><mn>0</mn></msub><mrow><mo fence="true">(</mo><msub><mi mathvariant="normal">C</mi><mn>2</mn></msub><msub><mi mathvariant="normal">H</mi><mn>5</mn></msub><mrow><mi mathvariant="normal">O</mi><mi mathvariant="normal">H</mi></mrow><mo fence="true">)</mo></mrow></mrow></mstyle></mtd></mtr><mtr><mtd><mstyle scriptlevel="0" displaystyle="true"><mrow></mrow></mstyle></mtd><mtd><mstyle scriptlevel="0" displaystyle="true"><mrow><mrow></mrow><mi mathvariant="normal">p</mi><mrow><mo fence="true">(</mo><msub><mi mathvariant="normal">C</mi><mn>2</mn></msub><msub><mi mathvariant="normal">H</mi><mn>5</mn></msub><mrow><mi mathvariant="normal">O</mi><mi mathvariant="normal">H</mi></mrow><mo fence="true">)</mo></mrow><mo>=</mo><mo>−</mo><mrow><mo fence="true">(</mo><mn>1.71</mn><mo>×</mo><mn>1</mn><msup><mn>0</mn><mrow><mo>−</mo><mn>4</mn></mrow></msup><mrow><mtext> </mtext><mi mathvariant="normal">a</mi><mi mathvariant="normal">t</mi><mi mathvariant="normal">m</mi></mrow><msup><mrow><mtext> </mtext><mi mathvariant="normal">s</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup><mo fence="true">)</mo></mrow><mo>×</mo><mn>900</mn><mrow><mtext> </mtext><mi mathvariant="normal">s</mi></mrow><mo>+</mo><mn>0.33</mn><mrow><mtext> </mtext><mi mathvariant="normal">a</mi><mi mathvariant="normal">t</mi><mi mathvariant="normal">m</mi></mrow></mrow></mstyle></mtd></mtr><mtr><mtd><mstyle scriptlevel="0" displaystyle="true"><mrow></mrow></mstyle></mtd><mtd><mstyle scriptlevel="0" displaystyle="true"><mrow><mrow></mrow><mi mathvariant="normal">p</mi><mrow><mo fence="true">(</mo><msub><mi mathvariant="normal">C</mi><mn>2</mn></msub><msub><mi mathvariant="normal">H</mi><mn>5</mn></msub><mrow><mi mathvariant="normal">O</mi><mi mathvariant="normal">H</mi></mrow><mo fence="true">)</mo></mrow><mo>=</mo><mn>0.176</mn><mrow><mtext> </mtext><mi mathvariant="normal">a</mi><mi mathvariant="normal">t</mi><mi mathvariant="normal">m</mi></mrow><msup><mrow><mtext> </mtext><mi mathvariant="normal">s</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup></mrow></mstyle></mtd></mtr><mtr><mtd><mstyle scriptlevel="0" displaystyle="true"><mrow></mrow></mstyle></mtd><mtd><mstyle scriptlevel="0" displaystyle="true"><mrow></mrow></mstyle></mtd></mtr></mtable><annotation encoding="application/x-tex">\begin{aligned} & \mathrm{k}=\frac{\mathrm{p}_0\left[\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}\right]-\mathrm{p}\left[\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}\right]}{\mathrm{t}}=\frac{250 \text { torr }-185 \text { torr }}{500 \mathrm{~s}}=0.13 \text { torr s }^{-1} \\ & \mathrm{k}=0.13 \text { torr s } \mathrm{s}^{-1} \times \frac{1 \mathrm{~atm}}{760 \text { torr }}=1.71 \times 10^{-4} \mathrm{~atm} \mathrm{~s}^{-1} \\ & \text { rate }=\mathbf{k} \\ & \mathrm{p}\left(\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}\right)=-\mathrm{kt}+\mathrm{p}_0\left(\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}\right) \\ & \mathrm{p}\left(\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}\right)=-\left(1.71 \times 10^{-4} \mathrm{~atm} \mathrm{~s}^{-1}\right) \times 900 \mathrm{~s}+0.33 \mathrm{~atm} \\ & \mathrm{p}\left(\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}\right)=0.176 \mathrm{~atm} \mathrm{~s}^{-1} \\ & \end{aligned} </annotation></semantics></math></span><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:12.2687em;vertical-align:-5.8843em;"></span><span class="mord"><span class="mtable"><span class="col-align-r"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:6.3843em;"><span style="top:-8.3843em;"><span class="pstrut" style="height:3.427em;"></span><span class="mord"></span></span><span style="top:-6.0769em;"><span class="pstrut" style="height:3.427em;"></span><span class="mord"></span></span><span style="top:-4.2509em;"><span class="pstrut" style="height:3.427em;"></span><span class="mord"></span></span><span style="top:-2.7509em;"><span class="pstrut" style="height:3.427em;"></span><span class="mord"></span></span><span style="top:-1.2268em;"><span class="pstrut" style="height:3.427em;"></span><span class="mord"></span></span><span style="top:0.2973em;"><span class="pstrut" style="height:3.427em;"></span><span class="mord"></span></span><span style="top:1.7973em;"><span class="pstrut" style="height:3.427em;"></span><span class="mord"></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:5.8843em;"><span></span></span></span></span></span><span class="col-align-l"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:6.3843em;"><span style="top:-8.3843em;"><span class="pstrut" style="height:3.427em;"></span><span class="mord"><span class="mord"></span><span class="mord mathrm">k</span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mrel">=</span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mord"><span class="mopen nulldelimiter"></span><span class="mfrac"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:1.427em;"><span style="top:-2.314em;"><span class="pstrut" style="height:3em;"></span><span class="mord"><span class="mord mathrm">t</span></span></span><span style="top:-3.23em;"><span class="pstrut" style="height:3em;"></span><span class="frac-line" style="border-bottom-width:0.04em;"></span></span><span style="top:-3.677em;"><span class="pstrut" style="height:3em;"></span><span class="mord"><span class="mord"><span class="mord mathrm">p</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">0</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mspace" style="margin-right:0.1667em;"></span><span class="minner"><span class="mopen delimcenter" style="top:0em;">[</span><span class="mord"><span class="mord mathrm">C</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">H</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">5</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">OH</span></span><span class="mclose delimcenter" style="top:0em;">]</span></span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mbin">−</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mord mathrm">p</span><span class="mspace" style="margin-right:0.1667em;"></span><span class="minner"><span class="mopen delimcenter" style="top:0em;">[</span><span class="mord"><span class="mord mathrm">C</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">H</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">5</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">OH</span></span><span class="mclose delimcenter" style="top:0em;">]</span></span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.686em;"><span></span></span></span></span></span><span class="mclose nulldelimiter"></span></span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mrel">=</span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mord"><span class="mopen nulldelimiter"></span><span class="mfrac"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:1.3214em;"><span style="top:-2.314em;"><span class="pstrut" style="height:3em;"></span><span class="mord"><span class="mord">500</span><span class="mord"><span class="mspace nobreak"> </span><span class="mord mathrm">s</span></span></span></span><span style="top:-3.23em;"><span class="pstrut" style="height:3em;"></span><span class="frac-line" style="border-bottom-width:0.04em;"></span></span><span style="top:-3.677em;"><span class="pstrut" style="height:3em;"></span><span class="mord"><span class="mord">250</span><span class="mord text"><span class="mord"> torr </span></span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mbin">−</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mord">185</span><span class="mord text"><span class="mord"> torr </span></span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.686em;"><span></span></span></span></span></span><span class="mclose nulldelimiter"></span></span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mrel">=</span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mord">0.13</span><span class="mord"><span class="mord text"><span class="mord"> torr s </span></span><span class="msupsub"><span class="vlist-t"><span class="vlist-r"><span class="vlist" style="height:0.8641em;"><span style="top:-3.113em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight"><span class="mord mtight">−</span><span class="mord mtight">1</span></span></span></span></span></span></span></span></span></span></span><span style="top:-6.0769em;"><span class="pstrut" style="height:3.427em;"></span><span class="mord"><span class="mord"></span><span class="mord mathrm">k</span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mrel">=</span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mord">0.13</span><span class="mord text"><span class="mord"> torr s </span></span><span class="mord"><span class="mord mathrm">s</span><span class="msupsub"><span class="vlist-t"><span class="vlist-r"><span class="vlist" style="height:0.8641em;"><span style="top:-3.113em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight"><span class="mord mtight">−</span><span class="mord mtight">1</span></span></span></span></span></span></span></span></span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mbin">×</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mord"><span class="mopen nulldelimiter"></span><span class="mfrac"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:1.3214em;"><span style="top:-2.314em;"><span class="pstrut" style="height:3em;"></span><span class="mord"><span class="mord">760</span><span class="mord text"><span class="mord"> torr </span></span></span></span><span style="top:-3.23em;"><span class="pstrut" style="height:3em;"></span><span class="frac-line" style="border-bottom-width:0.04em;"></span></span><span style="top:-3.677em;"><span class="pstrut" style="height:3em;"></span><span class="mord"><span class="mord">1</span><span class="mord"><span class="mspace nobreak"> </span><span class="mord mathrm">atm</span></span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.686em;"><span></span></span></span></span></span><span class="mclose nulldelimiter"></span></span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mrel">=</span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mord">1.71</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mbin">×</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mord">1</span><span class="mord"><span class="mord">0</span><span class="msupsub"><span class="vlist-t"><span class="vlist-r"><span class="vlist" style="height:0.8641em;"><span style="top:-3.113em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight"><span class="mord mtight">−</span><span class="mord mtight">4</span></span></span></span></span></span></span></span></span><span class="mord"><span class="mspace nobreak"> </span><span class="mord mathrm">atm</span></span><span class="mord"><span class="mord"><span class="mspace nobreak"> </span><span class="mord mathrm">s</span></span><span class="msupsub"><span class="vlist-t"><span class="vlist-r"><span class="vlist" style="height:0.8641em;"><span style="top:-3.113em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight"><span class="mord mtight">−</span><span class="mord mtight">1</span></span></span></span></span></span></span></span></span></span></span><span style="top:-4.2509em;"><span class="pstrut" style="height:3.427em;"></span><span class="mord"><span class="mord"></span><span class="mord text"><span class="mord"> rate </span></span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mrel">=</span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mord mathbf">k</span></span></span><span style="top:-2.7509em;"><span class="pstrut" style="height:3.427em;"></span><span class="mord"><span class="mord"></span><span class="mord mathrm">p</span><span class="mspace" style="margin-right:0.1667em;"></span><span class="minner"><span class="mopen delimcenter" style="top:0em;">(</span><span class="mord"><span class="mord mathrm">C</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">H</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">5</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">OH</span></span><span class="mclose delimcenter" style="top:0em;">)</span></span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mrel">=</span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mord">−</span><span class="mord"><span class="mord mathrm">kt</span></span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mbin">+</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mord"><span class="mord mathrm">p</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">0</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mspace" style="margin-right:0.1667em;"></span><span class="minner"><span class="mopen delimcenter" style="top:0em;">(</span><span class="mord"><span class="mord mathrm">C</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">H</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">5</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">OH</span></span><span class="mclose delimcenter" style="top:0em;">)</span></span></span></span><span style="top:-1.2268em;"><span class="pstrut" style="height:3.427em;"></span><span class="mord"><span class="mord"></span><span class="mord mathrm">p</span><span class="mspace" style="margin-right:0.1667em;"></span><span class="minner"><span class="mopen delimcenter" style="top:0em;">(</span><span class="mord"><span class="mord mathrm">C</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">H</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">5</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">OH</span></span><span class="mclose delimcenter" style="top:0em;">)</span></span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mrel">=</span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mord">−</span><span class="mspace" style="margin-right:0.1667em;"></span><span class="minner"><span class="mopen delimcenter" style="top:0em;"><span class="delimsizing size1">(</span></span><span class="mord">1.71</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mbin">×</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mord">1</span><span class="mord"><span class="mord">0</span><span class="msupsub"><span class="vlist-t"><span class="vlist-r"><span class="vlist" style="height:0.8641em;"><span style="top:-3.113em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight"><span class="mord mtight">−</span><span class="mord mtight">4</span></span></span></span></span></span></span></span></span><span class="mord"><span class="mspace nobreak"> </span><span class="mord mathrm">atm</span></span><span class="mord"><span class="mord"><span class="mspace nobreak"> </span><span class="mord mathrm">s</span></span><span class="msupsub"><span class="vlist-t"><span class="vlist-r"><span class="vlist" style="height:0.8641em;"><span style="top:-3.113em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight"><span class="mord mtight">−</span><span class="mord mtight">1</span></span></span></span></span></span></span></span></span><span class="mclose delimcenter" style="top:0em;"><span class="delimsizing size1">)</span></span></span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mbin">×</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mord">900</span><span class="mord"><span class="mspace nobreak"> </span><span class="mord mathrm">s</span></span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mbin">+</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mord">0.33</span><span class="mord"><span class="mspace nobreak"> </span><span class="mord mathrm">atm</span></span></span></span><span style="top:0.2973em;"><span class="pstrut" style="height:3.427em;"></span><span class="mord"><span class="mord"></span><span class="mord mathrm">p</span><span class="mspace" style="margin-right:0.1667em;"></span><span class="minner"><span class="mopen delimcenter" style="top:0em;">(</span><span class="mord"><span class="mord mathrm">C</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">2</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">H</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:0em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight">5</span></span></span></span><span class="vlist-s"></span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord"><span class="mord mathrm">OH</span></span><span class="mclose delimcenter" style="top:0em;">)</span></span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mrel">=</span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mord">0.176</span><span class="mord"><span class="mspace nobreak"> </span><span class="mord mathrm">atm</span></span><span class="mord"><span class="mord"><span class="mspace nobreak"> </span><span class="mord mathrm">s</span></span><span class="msupsub"><span class="vlist-t"><span 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