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But if you don't change your direction, and if you keep looking, you may end up where you are heading.
Learning Objectives
One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, such as the rate of change in the concentration of reactants or products with time, to discover the sequence of events that occur at the molecular level during a reaction. This molecular description is the mechanism of the reaction; it describes how individual atoms, ions, or molecules interact to form particular products. The stepwise changes are collectively called the reaction mechanism.
In an internal combustion engine, for example, isooctane reacts with oxygen to give carbon dioxide and water:
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It is more likely that a complex series of reactions takes place in a stepwise fashion. Each individual reaction, which is called an elementary reaction, involves one, two, or (rarely) three atoms, molecules, or ions. The overall sequence of elementary reactions is the mechanism of the reaction. The sum of the individual steps, or elementary reactions, in the mechanism must give the balanced chemical equation for the overall reaction.",-1),p=s("p",null,"The overall sequence of elementary reactions is the mechanism of the reaction.",-1),h=s("h2",{id:"_12-5-2-molecularity-and-the-rate-determining-step",tabindex:"-1"},[a("12-5-2: Molecularity and the Rate-Determining Step "),s("a",{class:"header-anchor",href:"#_12-5-2-molecularity-and-the-rate-determining-step","aria-hidden":"true"},"#")],-1),o=s("p",null,"To demonstrate how the analysis of elementary reactions helps us determine the overall reaction mechanism, we will examine the much simpler reaction of carbon monoxide with nitrogen 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It is more likely that a complex series of reactions takes place in a stepwise fashion. Each individual reaction, which is called an elementary reaction, involves one, two, or (rarely) three atoms, molecules, or ions. The overall sequence of elementary reactions is the mechanism of the reaction. 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In contrast, the rate law cannot be determined from the balanced chemical equation for the overall reaction (unless it is a single step mechanism and is therefore also an elementary step).")],-1),B=s("h2",{id:"_12-5-4-identifying-the-rate-determining-step",tabindex:"-1"},[a("12-5-4: Identifying the Rate-Determining Step "),s("a",{class:"header-anchor",href:"#_12-5-4-identifying-the-rate-determining-step","aria-hidden":"true"},"#")],-1),R=s("p",null,"Note the important difference between writing rate laws for elementary reactions and the balanced chemical equation of the overall reaction. Because the balanced chemical equation does not necessarily reveal the individual elementary reactions by which the reaction occurs, we cannot obtain the rate law for a reaction from the overall balanced chemical equation alone. In fact, it is the rate law for the slowest overall reaction, which is the same as the rate law for the slowest step in the reaction mechanism, the ratedetermining step, that must give the experimentally determined rate law for the overall reaction.This statement is true if one step is substantially slower than all the others, typically by a factor of 10 or more. If two or more slow steps have comparable rates, the experimentally determined rate laws can become complex. Our discussion is limited to reactions in which one step can be identified as being substantially slower than any other. The reason for this is that any process that occurs through a sequence of steps can take place no faster than the slowest step in the sequence. In an automotive assembly line, for example, a component cannot be used faster than it is produced. Similarly, blood pressure is regulated by the flow of blood through the smallest passages, the capillaries. Because movement through capillaries constitutes the rate-determining step in blood flow, blood pressure can be regulated by medications that cause the capillaries to contract or dilate. 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review","frontmatter":{"title":"Patterns of Organization and Methods of Development","description":"Literature methods of development article clip for review"},"headers":[{"level":2,"title":"Major Patterns of Organization","slug":"major-patterns-of-organization","link":"#major-patterns-of-organization","children":[]},{"level":2,"title":"General to Specific or Specific to General","slug":"general-to-specific-or-specific-to-general","link":"#general-to-specific-or-specific-to-general","children":[]},{"level":2,"title":"Does the Triangle Mean the Essay Keeps Getting More Specific or More Broad until the Very End?","slug":"does-the-triangle-mean-the-essay-keeps-getting-more-specific-or-more-broad-until-the-very-end","link":"#does-the-triangle-mean-the-essay-keeps-getting-more-specific-or-more-broad-until-the-very-end","children":[]},{"level":2,"title":"Are There Other Ways to Think about Organizing My 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organization can help your readers follow the ideas within your essay and your paragraphs, but they can also work as methods of development to help you recognize and further develop ideas and relationships in your writing. Here are some strategies that can help you with both organization and development in your essays.

Read the following sentences:
How did it feel to read the above list? A bit confusing, I would guess. Thatâs because the steps for making a pie were not well organized, and the steps donât include enough detail for us to know exactly what we should do. (Like what are the dry and liquid ingredients?) We all know that starting instructions from the beginning and giving each detailed step in the order it should happen is vital to having a good outcome, in this case a yummy pie! But itâs not always so simple to know how to organize or develop ideas, and sometimes thereâs more than one way, which complicates things even further.
First, letâs take a look at a couple of ways to think about organization.
It might be useful to think about organizing your topic like a triangle:

The first triangle represents starting with the most general, big picture information first, moving then to more detailed and often more personal information later in the paper. The second triangle represents an organizational structure that starts with the specific, small scale information first and then moves to the more global, big picture stuff.
For example, if your topic is traffic in Vancouver, British Columbia, an essay that uses the general-to-specific organizational structure might begin this way:
Many people consider Vancouver, British Columbia, to be a relaxed place to live. They would be shocked to know how bad the traffic is traveling major arteries into the city and even driving around the city itself.
An essay that uses the specific-to-general structure might start like this:
Transit is crowded, parking is expensive, and vehicles stop and go through the main streets of the city of Vancouver, British Columbia, and that is just once travelers brave the crowded arteries to enter the city; Vancouverâs traffic problem does not lend itself to the relaxed atmosphere many believe the city to have.
Whatâs the difference between these two introductions? And how might they appeal to the intended audience for this essay in different ways? The first introduction is looking at the big picture of the problem and mentions pollutionâs impact on all citizens in Portland, while the second introduction focuses on one specific family. The first helps readers see how vast the problem really is, and the second helps connect readers to a real family, making an emotional appeal from the very beginning. Neither introduction is necessarily better. Youâll choose one over the other based on the kind of tone youâd like to create and how youâd like to affect your audience. Itâs completely up to you to make this decision.
The triangle is kind of a general guide, meaning youâre allowed to move around within it all you want. For example, itâs possible that each of your paragraphs will be its own triangle, starting with the general or specific and moving out or in. However, if you begin very broadly, it might be effective to end your essay in a more specific, personal way. And if you begin with a personal story, consider ending your essay by touching on the global impact and importance of your topic.
Yes! Rather than thinking about which of your ideas are most specific or personal or which are more broad or universal, you might consider one of the following ways of organizing your ideas:
The section on Methods of Development, below, offers more detail about some of these organizational patterns, along with some others.
Choose one of the following topics, and practice writing a few opening sentences like we did above, once using the general-to-specific format and once using the specific-to-general. Which do you like better? What audience would be attracted to which one? Share with peers to see how others tackled this challenge. How would you rewrite their sentences? Why? Discuss your changes and listen to how your peers have revised your sentences. Taking in other peopleâs ideas will help you see new ways to approach your own writing and thinking.
Topics:
The methods of development covered here are best used as ways to look at whatâs already happening in your draft and to consider how you might emphasize or expand on any existing patterns. You might already be familiar with some of these patterns because teachers will sometimes assign them as the purpose for writing an essay. For example, you might have been asked to write a cause-and-effect essay or a comparison-and-contrast essay.
Itâs important to emphasize here that patterns of organization or methods of developing content usually happen naturally as a consequence of the way the writer engages with and organizes information while writing. That is to say, most writers donât sit down and say, âI think Iâll write a cause-and-effect essay today.â Instead, a writer might be more likely to be interested in a topic, say, the state of drinking water in the local community, and as the writer begins to explore the topic, certain cause-and-effect relationships between environmental pollutants and the community water supply may begin to emerge.
So if these patterns just occur naturally in writing, whatâs the use in knowing about them? Well, sometimes you might be revising a draft and notice that some of your paragraphs are a bit underdeveloped. Maybe they lack a clear topic, or maybe they lack support. In either case, you can look to these common methods of development to find ways to sharpen those vague topics or to add support where needed. Do you have a clear cause statement somewhere but you havenât explored the effects? Are you lacking detail somewhere where a narrative story or historical chronology can help build reader interest and add support? Are you struggling to define an idea that might benefit from some comparison or contrast? Read on to consider some of the ways that these strategies can help you in revision.
Do you see a potential cause-and-effect relationship developing in your draft? The cause-and-effect pattern may be used to identify one or more causes followed by one or more effects or results. Or you may reverse this sequence and describe effects first and then the cause or causes. For example, the causes of water pollution might be followed by its effects on both humans and animals. You may use obvious transitions to clarify cause and effect, such as âWhat are the results? Here are some of themâŠâ or you might simply use the words cause, effect, and result, to cue the reader about your about the relationships that youâre establishing.
At some point does your essay explore a problem or suggest a solution? The problem-solution pattern is commonly used in identifying something thatâs wrong and in contemplating what might be done to remedy the situation. There are probably more ways to organize a problem-solution approach, but but here are three possibilities:
When the solution is stated at the end of the paper, the pattern is sometimes called the delayed proposal. For a hostile audience, it may be effective to describe the problem, show why other solutions do not work, and finally suggest the favored solution. You can emphasize the words problem and solution to signal these sections of your paper for your reader.
Do you need to develop support for a topic where telling a story can illustrate some important concept for your readers? Material arranged chronologically is explained as it occurs in time. A chronological or narrative method of development might help you find a way to add both interest and content to your essay. Material arranged chronologically is explained as it occurs in time. This pattern may be used to establish what has happened. Chronology or narrative can be a great way to introduce your essay by providing a background or history behind your topic. Or you may want to tell a story to develop one or more points in the body of your essay. You can use transitional words like then, next, and finally to make the parts of the chronology clear.
Are you trying to define something? Do you need your readers to understand what something is and what it is not? The comparison-and-contrast method of development is particularly useful in extending a definition, or anywhere you need to show how a subject is like or unlike another subject. For example, the statement is often made that drug abuse is a medical problem instead of a criminal justice issue. An author might attempt to prove this point by comparing drug addiction to AIDS, cancer, or heart disease to redefine the term âaddictionâ as a medical problem. A statement in opposition to this idea could just as easily establish contrast by explaining all the ways that addiction is different from what we traditionally understand as an illness. In seeking to establish comparison or contrast in your writing, some words or terms that might be useful are by contrast, in comparison, while, some, and others.
Summary
These four methods of developmentâcause and effect, problem-solution, chronology or narrative, and comparison and contrastâare just a few ways to organize and develop ideas and content in your essays. Itâs important to note that they should not be a starting point for writers who want to write something authenticâsomething that they care deeply about. Instead, they can be a great way to help you look for whatâs already happening with your topic or in a draft, to help you to write more, or to help you reorganize some parts of an essay that seem to lack connection or feel disjointed. Look for organizational patterns when youâre reading work by professional writers. Notice where they combine strategies (e.g., a problem-solution pattern that uses cause-and-effect organization, or a comparison-contrast pattern that uses narrative or chronology to develop similarities or differences). Pay attention to how different writers emphasize and develop their main ideas, and use what you find to inspire you in your own writing. Better yet, work on developing completely new patterns of your own.
Reference
This chapter was adapted from âPatterns of Organization and Methods of Developmentâ in The Word on College Reading and Writing by Carol Burnell, Jaime Wood, Monique Babin, Susan Pesznecker, and Nicole Rosevear, which is licensed under a CC BY-NC 4.0 Licence. Adapted by Allison Kilgannon.
âPeach and lavender pieâ by Heather Joan is licensed under a CC BY-NC-ND 2.0 Licence.
âGeneral to Specific vs. Specific to General Trianglesâ by Carol Burnell, Jaime Wood, Monique Babin, Susan Pesznecker, and Nicole Rosevear is under a CC BY-NC 4.0 Licence.
Kilgannon, Allison. âPatterns of Organization and Methods of Development.â Opentextbc.ca, 20 Aug. 2021, opentextbc.ca/advancedenglish/chapter/patterns-of-organization-and-methods-of-development/#:~:text=These four methods of development.
This table of vocabularies are from "Sadlier Vocabulary Workshop-Level G (Unit 4)" with their corresponding textbook definitions and part of speeches (from some of them) made into a collection.
| Vocabulary | Definition |
|---|---|
| Atrophy | (n.) the wasting away of a body organ or tissue; any progressive decline or failure; (v.) to waste away |
| Bastion | A fortified place, stronghold |
| Concord | A state of agreement, harmony, unanimity; a treaty, pact, covenant |
| Consummate | (adj.) complete or perfect in the highest degree; (v.) to bring to a state of completion or perfection |
| Disarray | (n.) disorder, confusion; (v.) to throw into disorder |
| Exigency | Urgency, pressure; urgent demand, pressing need; an emergency |
| Flotsam | Floating debris; homeless, impoverished people |
| Frenetic | Frenzied, highly agitated |
| Glean | To gather bit by bit; to gather small quantities of grain left in a field by the reapers. |
| Grouse | (n.) A type of game bird; a complaint; (v.) to complain, grumble |
| Incarcerate | To imprison, confine, jail |
| Incumbent | (adj.) obligatory, required; (n.) one who holds a specific office at the time spoken of |
| Jocular | Humorous, jesting, jolly, joking |
| Ludicrous | Ridiculous, laughable, absurd |
| Mordant | Biting or caustic in thought, manner, or style; sharply or bitterly harsh. |
| Nettle | (n.) a prickly or stinging plant; (v.) to arouse displeasure, impatience, or anger; to vex or irritate severely |
| Pecuniary | Consisting of or measured in money; of or related to money |
| Pusillanimous | Contemptibly cowardly or mean-spirited |
| Recumbent | In a reclining position, lying down, in the posture of one sleeping or resting. |
| Stratagem | A scheme to outwit or deceive an opponent or to gain and end. |
Reference
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2","slug":"solution-2","link":"#solution-2","children":[]}]}],"relativePath":"getting-started.md","lastUpdated":1677686831000}'),e={name:"getting-started.md"},l=o(` Git push results in "Authentication Failedâ
Issue
bash$ git push +Username for 'https://github.com': \${{ GITHUB_USERNAME }} +Password for 'https://andatoshiki@github.com': \${{ GITHUB_PASSWORD }} # or GitHub personal access token +remote: Invalid username or password. +fatal: Authentication failed for 'https://github.com/andatoshiki/andatoshiki.git/' +$ git push +Username for 'https://github.com': \${{ GITHUB_USERNAME }} +Password for 'https://andatoshiki@github.com': \${{ GITHUB_PASSWORD }} # or GitHub personal access token +remote: Invalid username or password. +fatal: Authentication failed for 'https://github.com/andatoshiki/andatoshiki.git/' +
git pushto GitHub remote branch failed via https protocolSolution
Solution 1
If you enabled two-factor authentication in your GitHub account you won't be able to push via HTTPS using your accounts password. Instead you need to generate a personal access token. This can be done in the application settings of your GitHub account. Using this token as your password should allow you to push to your remote repository via HTTPS. Use your username as usual.
You may also need to update the origin for your repository if it is set to HTTPS. Do this to switch to SSH:
bash$ git remote -v +$ git remote set-url origin git@github.com:$USERNAME/$REPONAME.git +$ git remote -v +$ git remote set-url origin git@github.com:$USERNAME/$REPONAME.git +Solution 2
GitHub username & password/access token mismatched due to prior temporary Git config setup â Reset Git global username & email config or in current repository
To set your global username/email configuration:
- Open the command line.
- Set your username:
git config --global user.name "FIRST_NAME LAST_NAME"- Set your email address:
git config --global user.email "MY_NAME@example.com"To set repository-specific username/email configuration:
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- From the command line, change into the repository directory.
- Set your username:
git config user.name "FIRST_NAME LAST_NAME"- Set your email address:
git config user.email "MY_NAME@example.com"- Verify your configuration by displaying your configuration file:
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