From 672969a74adade73fdc6620a21ff321f19061ea9 Mon Sep 17 00:00:00 2001 From: Anda Toshiki Date: Thu, 2 Mar 2023 15:08:12 +0800 Subject: [PATCH] doc: add new problems set for chemistry and update titles of sidebar --- .husky/commit-msg | 0 docs/.vitepress/config/sidebar.ts | 4 ++-- docs/academic/chemistry/index.md | 0 docs/academic/chemistry/notes/12-5.md | 0 docs/academic/chemistry/problems/02-20.md | 0 docs/academic/chemistry/problems/03-02-2.md | 17 +++++++++------ docs/academic/chemistry/problems/03-02-3.md | 23 +++++++++++++++++++++ scripts/create-chapter.sh | 0 8 files changed, 36 insertions(+), 8 deletions(-) mode change 100755 => 100644 .husky/commit-msg mode change 100755 => 100644 docs/academic/chemistry/index.md mode change 100755 => 100644 docs/academic/chemistry/notes/12-5.md mode change 100755 => 100644 docs/academic/chemistry/problems/02-20.md create mode 100644 docs/academic/chemistry/problems/03-02-3.md mode change 100755 => 100644 scripts/create-chapter.sh diff --git a/.husky/commit-msg b/.husky/commit-msg old mode 100755 new mode 100644 diff --git a/docs/.vitepress/config/sidebar.ts b/docs/.vitepress/config/sidebar.ts index cae5f1d9..9cd66371 100644 --- a/docs/.vitepress/config/sidebar.ts +++ b/docs/.vitepress/config/sidebar.ts @@ -23,8 +23,8 @@ export const sidebar: DefaultTheme.Config['sidebar'] = { collapsed: true, items: [ { text: 'Problem: 02-20', link: '/academic/chemistry/problems/02-20' }, - { text: 'Problem: 03-02-1', link: '/academic/chemistry/problems/03-02' }, - { text: 'Problem: 03-02-2', link: '' }, + { text: 'Problem: 03-02-1', link: '/academic/chemistry/problems/03-02-1' }, + { text: 'Problem: 03-02-2', link: '/academic/chemistry/problems/03-02-2' }, ], }, ], diff --git a/docs/academic/chemistry/index.md b/docs/academic/chemistry/index.md old mode 100755 new mode 100644 diff --git a/docs/academic/chemistry/notes/12-5.md b/docs/academic/chemistry/notes/12-5.md old mode 100755 new mode 100644 diff --git a/docs/academic/chemistry/problems/02-20.md b/docs/academic/chemistry/problems/02-20.md old mode 100755 new mode 100644 diff --git a/docs/academic/chemistry/problems/03-02-2.md b/docs/academic/chemistry/problems/03-02-2.md index 3289593e..907c4d67 100644 --- a/docs/academic/chemistry/problems/03-02-2.md +++ b/docs/academic/chemistry/problems/03-02-2.md @@ -3,19 +3,23 @@ ## Question The rate law for a particular reaction is rate $=k[\mathrm{XY}]^2$. In an experiment, the initial rate of the reaction is determined to be $0.16 \mathrm{~mol} /(\mathrm{L} \cdot \mathrm{s})$ when the initial concentration of $\mathrm{XY}$ is $0.40 \mathrm{~mol} / \mathrm{L}$. -- What is the value of the rate constant, $k$, for the reaction? - - [ ] $0.10 \mathrm{~L} /(\mathrm{mol} \cdot \mathrm{s})$ - - [ ] $0.40 \mathrm{~L} /(\mathrm{mol} \cdot \mathrm{s})$ - - [x] $1.0 \mathrm{~L} /(\mathrm{mol} \cdot \mathrm{s})$ - - [ ] $2.5 \mathrm{~L} /(\mathrm{mol} \cdot \mathrm{s})$ + +- What is the value of the rate constant, $k$, for the reaction? + - [ ] $0.10 \mathrm{~L} /(\mathrm{mol} \cdot \mathrm{s})$ + - [ ] $0.40 \mathrm{~L} /(\mathrm{mol} \cdot \mathrm{s})$ + - [x] $1.0 \mathrm{~L} /(\mathrm{mol} \cdot \mathrm{s})$ + - [ ] $2.5 \mathrm{~L} /(\mathrm{mol} \cdot \mathrm{s})$ ## Solution lo tind the value of the rate constant for the reaction, let's first solve the rate law for $k$ : + $$ k=\frac{\text { rate }}{[\mathrm{XY}]^2} $$ + Next, let's plug in the initial rate and concentration given in the text: + $$ \begin{aligned} k & =\frac{0.16 \mathrm{~mol} /(\mathrm{L} \cdot \mathrm{s})}{(0.40 \mathrm{~mol} / \mathrm{L})^2} \\ @@ -23,5 +27,6 @@ k & =\frac{0.16 \mathrm{~mol} /(\mathrm{L} \cdot \mathrm{s})}{(0.40 \mathrm{~mol & =1.0 \mathrm{~L} /(\mathrm{mol} \cdot \mathrm{s}) \end{aligned} $$ + So, the value of the rate constant for the reaction is -$1.0 \mathrm{~L} /(\mathrm{mol} \cdot \mathrm{s})$ \ No newline at end of file +$1.0 \mathrm{~L} /(\mathrm{mol} \cdot \mathrm{s})$ diff --git a/docs/academic/chemistry/problems/03-02-3.md b/docs/academic/chemistry/problems/03-02-3.md new file mode 100644 index 00000000..4c6c5202 --- /dev/null +++ b/docs/academic/chemistry/problems/03-02-3.md @@ -0,0 +1,23 @@ +# Problem 03-02-3 + +## Question + +$$ +2 \mathrm{X}(g)+2 \mathrm{Y}(g) \rightarrow \mathrm{Q}(g)+2 \mathrm{R}(g) +$$ + +The reaction represented above is found to be second order with respect to $\mathrm{X}$ and first order with respect to $\mathrm{Y}$. + +What happens to the rate of the reaction when $[\mathrm{X}]$ is halved and $[\mathrm{Y}]$ is doubled? + +- [ ] It increases by a factor of 4. +- [x] It decreases by a factor of 2. +- [ ] It decreases by a factor of 4. +- [ ] It does not change. + +## Solution + +To solve this problem, let's first write out the rate law for the reaction. According to the text, the reaction is second order with respect to $\mathrm{X}$ and first order with respect to $\mathrm{Y}$, so the rate law is rate $=k[\mathrm{X}]^2[\mathrm{Y}]$ + +Now, let's think about how the rate changes when $[\mathrm{X}]$ is halved and $[\mathrm{Y}]$ is doubled. Since $[\mathrm{X}]$ is raised to the second power in the rate law, halving $[\mathrm{X}]$ decreases the reaction rate by a factor of 4 . Similarly, since $[\mathrm{Y}]$ is raised to the first power, doubling $[\mathrm{Y}]$ increases the reaction rate by a factor of 2 . Combined, these changes result in the reaction rate decreasing by a factor of 2 overall. +So, when $[\mathrm{X}]$ is halved and $[\mathrm{Y}]$ is doubled, the rate of the reaction decreases by a factor of 2 . diff --git a/scripts/create-chapter.sh b/scripts/create-chapter.sh old mode 100755 new mode 100644